Controlling Infrared Light with Phase-Change Materials

In the 1950s, the field of electronics began to change when the transistor replaced vacuum tubes in computers. The change, which entailed replacing large and slow components with small and fast ones, was a catalyst for the enduring trend of miniaturi­zation in computer design. No such revolution has yet hit the field of infrared optics, which remains reliant on bulky moving parts that preclude building small systems. However, a team of researchers at MIT Lincoln Labora­tory, together with Juejun Hu and graduate students from MIT’s Department of Materials Science and Engi­neering, is devising a way to control infrared light by using phase-change materials instead of moving parts. These materials have the ability to change their optical properties when energy is added to them.

This 8-inch wafer contains phase-change pixels that can be controlled to modulate light. Researchers are studying the properties and behaviors of the pixels to inform the creation of future devices that use phase-change materials. (Source: N. Fandel, MIT)

“There are multiple possible ways where this material can enable new photonic devices that impact people’s lives,” says Hu. “For example, it can be useful for energy-efficient optical switches, which can improve network speed and reduce power consump­tion of internet data centers. It can enable recon­figurable meta-optical devices, such as compact, flat infrared zoom lenses without mechanical moving parts. It can also lead to new computing systems, which can make machine learning faster and more power-efficient compared to current solutions.”

A fundamental property of phase-change materials is that they can change how fast light travels through them – the refractive index. “There are already ways to modulate light using a refractive index change, but phase-change materials can change almost 1,000 times better,” says Jeffrey Chou, a team member formerly in the labora­tory’s Advanced Materials and Micro­systems Group. The team success­fully controlled infrared light in multiple systems by using a new class of phase-change material containing the elements germanium, antimony, selenium, and tellurium, known as GSST.

A phase-change material’s magic occurs in the chemical bonds that tie its atoms together. In one phase state, the material is crystal­line, with its atoms arranged in an organized pattern. This state can be changed by applying a short, high-temperature spike of thermal energy to the material, causing the bonds in the crystal to break down and then reform in a more random, or amorphous, pattern. To change the material back to the crystal­line state, a long- and medium-tempera­ture pulse of thermal energy is applied.

“This changing of the chemical bonds allows for different optical pro­perties to emerge, similar to the differences between coal (amorphous) and diamond (crystalline),” says Christopher Roberts, another Lincoln Labora­tory member of the research team. “While both materials are mostly carbon, they have vastly different optical properties.” Currently, phase-change materials are used for industry applications, such as Blu-ray tech­nology and rewritable DVDs, because their properties are useful for storing and erasing a large amount of information. But so far, no one has used them in infrared optics because they tend to be trans­parent in one state and opaque in the other.

If light cannot pass through one of the states, then that light cannot be ad­equately controlled for a range of uses; instead, a system would only be able to work like an on/off switch, allowing light to either pass through the material or not pass through at all. However, the research team found that that by adding the element selenium to the original material (GST), the material’s absorption of infrared light in the crystal­line phase decreased drama­tically – in essence, changing it from an opaque coal-like material to a more transparent diamond-like one. What’s more, the large difference in the refractive index of the two states affects the propa­gation of light through them.

“This change in refrac­tive index, without intro­ducing optical loss, allows for the design of devices that control infrared light without the need for mechanical parts,” Roberts says. As an example, imagine a laser beam that is pointing in one direction and needs to be changed to another. In current systems, a large mechanical gimbal would physically move a lens to steer the beam to another position. A thin-film lens made of GSST would be able change positions by elec­trically repro­gramming the phase-change materials, enabling beam steering with no moving parts.

The team has already tested the material success­fully in a moving lens. They have also demonstrated its use in infrared hyper­spectral imaging, which is used to analyze images for hidden objects or information, and in a fast optical shutter that was able to close in nano­seconds. The potential uses for GSST are vast, and an ultimate goal for the team is to design recon­figurable optical chips, lenses, and filters, which currently must be rebuilt from scratch each time a change is required. Once the team is ready to move the material beyond the research phase, it should be fairly easy to transition it into the commercial space. Because it’s already compatible with standard micro­electronic fabri­cation processes, GSST components could be made at a low cost and in large numbers.

Recently, the labora­tory obtained a combina­torial sputtering chamber — a state-of-the-art machine that allows researchers to create custom materials out of indi­vidual elements. The team will use this chamber to further optimize the materials for improved relia­bility and switching speeds, as well as for low-power appli­cations. They also plan to experiment with other materials that may prove useful in controlling visible light. The next steps for the team are to look closely into real-world applications of GSST and under­stand what those systems need in terms of power, size, switching speed, and optical contrast.

“The impact [of this research] is twofold,” Hu says. “Phase-change materials offer a dramatically enhanced refractive index change compared to other physical effects – induced by electric field or tempera­ture change, for instance – thereby enabling extremely compact repro­grammable optical devices and circuits. Our demonstration of bistate optical trans­parency in these materials is also significant in that we can now create high-perfor­mance infrared components with minimal optical loss.” The new material, Hu continues, is expected to open up an entirely new design space in the field of infrared optics. (Source: MIT)

Reference: Y. Zhang et al.: Reshaping light: reconfigurable photonics enabled by broadband low-loss optical phase change materials, Proc. SPIE MNSSA XI, 109820Q (2019); DOI: 10.1117/12.2513385

Link: Lincoln Laboratory, Massachusetts Institute of Technology, Cambridge, USA

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